Dibenzyl ferrocene-1,1′-dicarboxylate
نویسندگان
چکیده
منابع مشابه
Dibenzyl ferrocene-1,1′-dicarboxylate
In the title compound, [Fe(C(13)H(11)O(2))(2)], there are markedly different orientations of the two phenyl-meth-oxy-carbonyl substituents [O-C-C-C torsion angles = 84.5 (3) and 139.6 (2)°]. These orientations are mediated by a number of inter-molecular C-H⋯O inter-actions, which result in a one-dimensional hydrogen-bonded network of mol-ecules.
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In the title compound, C(16)H(14)S(5), the non-bonded intra-molecular distances between the non-terminal S atoms are 2.808 (16) and 2.784 (16) Å, shorter than the typical distance of 2.9 Å. One phenyl ring participates in an offset π-π inter-action with another phenyl ring related by a centre of inversion; the inter-planar distance is 3.41 (2) Å. The crystal structure also exhibits edge-to-face...
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A cyclam (1,4,8,11-tetraazacyclotetradecane)-based macrocycle bearing two benzyl and two 2-hydroxy-3,5-di-tert-butylbenzyl pendent arms was synthesized and characterized using spectroscopic techniques and single crystal X-ray diffraction. The macrocycle crystallizes in the triclinic space group P-1, with the asymmetric unit containing one-half of the molecule. The structure is stabilized by hyd...
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The cation of the title salt, C(22)H(21)N(2) (+)·Cl(-), contains a planar benzimidazolium unit (r.m.s. deviation = 0.02 Å); the phenyl rings of the benzyl substituents form dihedral angles of 68.2 (1) and 79.7 (1)° with the plane of the benzimidazolium fragment.
متن کامل3,3′-Dibenzyl-1,1′-ethylenediimidazolium dibromide
In the title compound, C(22)H(24)N(4) (2+)·2Br(-), the imidazolium dication is located on a crystallographic inversion center. The imidazole and benzene rings make a dihedral angle of 73.1 (9)°. In the crystal, non-classical inter-molecular C-H⋯Br hydrogen bonds link the ion pairs into a two-dimensional network.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811016588